Preparing Alkyl Halides from Alcohols : Reacting Alcohols with Phosphorus Halides |
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date: 26-7-2019
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Alcohols react with liquid phosphorus(III) chloride (also called phosphorus trichloride) to yield chloroalkanes.
Alcohols also violently react with solid phosphorus(V) chloride (phosphorus pentachloride) at room temperature, producing clouds of hydrogen chloride gas. While it is not a good approach to make chloroalkanes, it is a good test for the presence of -OH groups. To show that a substance was an alcohol, you would first have to eliminate all the other groups that also react with phosphorus(V) chloride. For example, carboxylic acids (containing the -COOH group) also react with it (because of the -OH in -COOH) as does water (H-OH).
If you have a neutral liquid not contaminated with water, and clouds of hydrogen chloride are produced when you add phosphorus(V) chloride, then you have an alcohol group present.
There are also side reactions involving the POCl3 reacting with the alcohol.
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