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Date: 28-8-2018
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Date: 14-10-2020
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Date: 2-8-2019
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A carbene such as methlyene will react with an alkene which will break the double bond and result with a cyclopropane. The reaction will usually leave stereochemistry of the double bond unchanged. As stated before, carbenes are generally formed along with the main reaction; hence the starting material is diazomethane not methylene.
In the above case cis-2-butene is converted to cis-1,2-dimethylcyclopropane. Likewise, below the trans configuration is maintained.
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إدارة الغذاء والدواء الأميركية تقرّ عقارا جديدا للألزهايمر
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شراء وقود الطائرات المستدام.. "الدفع" من جيب المسافر
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العتبة العبّاسيّة: البحوث الّتي نوقشت في أسبوع الإمامة استطاعت أن تثري المشهد الثّقافي
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