POLYURETHANES

Polyurethanes are produced by the condensation reaction of a polyol and a diisocyanate:

No by-product is formed from this reaction. Toluene diisocyanate is a widely used monomer. Diols and triols produced from the reaction of glycerol and ethylene oxide or propylene oxide are suitable for producing polyurethanes.

Polyurethane polymers are either rigid or flexible, depending on the type of the polyol used. For example, triols derived from glycerol and propylene oxide are used for producing block slab foams. These polyols have moderate reactivity because the hydroxy groups are predominantly secondary. More reactive polyols (used to produce molding polyurethane foams) are formed by the reaction of polyglycols with ethylene oxide to give the more reactive primary group:

Other polyhydric compounds with higher functionality than glycerol (three-OH) are commonly used. Examples are sorbitol (six-OH) and sucrose (eight-OH). Triethanolamine, with three OH groups, is also used. Diisocyanates generally employed with polyols to produce polyurethanes are 2,4-and 2,6-toluene diisocyanates prepared from dinitrotoluenes

A different diisocyanate used in polyurethane synthesis is methylene diisocyanate (MDI), which is prepared from aniline and formaldehyde. The diamine product is reacted with phosgene to get MDI.

The physical properties of polyurethanes vary with the ratio of the polyol to the diisocyanate. For example, tensile strength can be adjusted within a range of 1,200–600 psi; elongation, between 150–800%.

Improved polyurethane can be produced by copolymerization. Block copolymers of polyurethanes connected with segments of isobutylenes exhibit high-temperature properties, hydrolytic stability, and barrier characteristics.

The hard segments of polyurethane block polymers consist of (–RNHCOO)–n, where R usually contains an aromatic moiety.

مواضيع ذات صلة

تقدير الكتل المولارية من إتزان الترسب

الأسموزية والديلزة Osmosis and dialysis

الحجم والشكل

الوزن الجزيئي للبوليمرات

البوليمرات المؤلفة من سلاسل رئيسة لا عضوية

البوليمرات ذات مجموعة الروابط الإقترانية

تصنيف مركبات الجزيئات الضخمة ذات السلاسل اللامتجانسة

تصنيف مركبات الجزيئات الضخمة الحاوية على سلاسل كربونية

تصنيف وتسمية مركبات الجزيئات الضخمة

الشكل الهندسي للبوليمر

البوليمرات المشتركة

البوليمرات المنتظمة فراغياً