Poly(E-caprolactone) or poly(6-hydroxy-hexanoate) (PCL)

PCL is a biodegradable polyester obtained from raw materials originating from petroleum, through ring opening polymerization of the lactone with suitable catalysts (Figure 2).

It has good resistance to water and organic solvents. PCL is a polymer stable against abiotic hydrolysis, which occurs slowly with molecular weight decrease. Its melting temperature is low, as its viscosity, facilitating its thermal processing. PCL may present spherulitic structure. It is a soft and flexible polymer, that may be used in blends with other biodegradable polymers, such as starch. A major global manufacturer is Solvay (Capa, 5,000 t per year). Some applications are foamed food trays, bags, bioabsorbable medical items, replacement of gypsum in the treatment of broken bones, etc.

PCL may be degraded by many microorganisms, including bacteria and fungi, that are spread by soils and water bodies. However, an initial stage of abiotic hydrolysis appears to be necessary. The rates of hydrolysis and biodegradation depend on  molecular weight and crystallinity. Pronounced biodegradation occurs with molecular weights below about 5,000 g-mol^-1. Abiotic and biotic degradation take place preferentially in the amorphous phase. Certain PCL-depolymerases, such as Pseudomonas lipase, can hydrolyse both amorphous and crystalline PCL phases. Enzymes from the two major classes of excreted esterases-lipases and cutinases - are able to degrade PCL and its blends .Biodegradation causes surface erosion, without reduction of molecular weight.

مواضيع ذات صلة

تقدير الكتل المولارية من إتزان الترسب

الأسموزية والديلزة Osmosis and dialysis

الحجم والشكل

الوزن الجزيئي للبوليمرات

البوليمرات المؤلفة من سلاسل رئيسة لا عضوية

البوليمرات ذات مجموعة الروابط الإقترانية

تصنيف مركبات الجزيئات الضخمة ذات السلاسل اللامتجانسة

تصنيف مركبات الجزيئات الضخمة الحاوية على سلاسل كربونية

تصنيف وتسمية مركبات الجزيئات الضخمة

الشكل الهندسي للبوليمر

البوليمرات المشتركة

البوليمرات المنتظمة فراغياً