Nitrogen Compounds

   Organic nitrogen compounds occur in crude oils either in a simple heterocyclic form as in pyridine (C₅H₅N) and pyrrole (C₄H₅N), or in a complex structure as in porphyrin. The nitrogen content in most crudes is very low and does not exceed 0.1 wt%. In some heavy crudes, however, the nitrogen content may reach up to 0.9 wt %.l8 Nitrogen compounds are more thermally stable than sulfur compounds and accordingly are concentrated in heavier petroleum fractions and residues. Light petroleum streams may contain trace amounts of nitrogen compounds, which should be removed because they poison many processing catalysts. During hydrotreatment of petroleum fractions, nitrogen compounds are hydrodenitrogenated to ammonia and the corresponding hydrocarbon. For example, pyridine is denitrogenated to ammonia and pentane:

Nitrogen compounds in crudes may generally be classified into basic and non-basic categories. Basic nitrogen compounds are mainly those having a pyridine ring, and the non-basic compounds have a pyrrole structure. Both pyridine and pyrrole are stable compounds due to their aromatic nature.  The following are examples of organic nitrogen compounds.

Basic Nitrogen Compounds

Non-Basic Nitrogen Compounds

Porphyrins are non-basic nitrogen compounds. The porphyrin ring system is composed of four pyrrole rings joined by =CH-groups. The entire ring system is aromatic. Many metal ions can replace the pyrrole hydrogens and form chelates. The chelate is planar around the metal ion and resonance results in four equivalent bonds from the nitrogen atoms to the metal. Almost all crude oils and bitumens contain detectable amounts of vanadyl and nickel porphyrins. The following shows a porphyrin structure:

Separation of nitrogen compounds is difficult, and the compounds are susceptible to alteration and loss during handling. However, the basic lowmolecular weight compounds may be extracted with dilute mineral acids.

مواضيع ذات صلة

سلوك المعادن الطينية في علاقتها مع الماء

تصنيف النفط الخام Classification of Crude Oils

التحليل المطلق Ultimate Analysis

المكونات الرئيسية للنفط الخام الموجود في منطقة القيارة

نفط خام القيار

النفط الخام ومكوناته

النفط والطاقة Oil and Energy

مزائج اسفلت – اسفلتين

أساليب تحوير المواصفات الريولوجية للاسفلت

صفات الاسفلت الريولوجية Properties of Asphalt Rheological

استخدامات الاسفلت Asphalt Uses of

التركيب الكيميائي للاسفلت Chemical Composition of Asphalt