Solutions and Colloids

The major component of a solution is called the solvent. The minor component of a solution is called the solute. By major and minor we mean whichever component has the greater presence by mass or by moles. Sometimes this becomes confusing, especially with substances with very different molar masses. However, here we will confine the discussion to solutions for which the major component and the minor component are obvious.

Solutions exist for every possible phase of the solute and the solvent. Salt water, for example, is a solution of solid NaCl in liquid water; soda water is a solution of gaseous CO₂ in liquid water, while air is a solution of a gaseous solute (O₂) in a gaseous solvent (N₂). In all cases, however, the overall phase of the solution is the same phase as the solvent.

One important concept of solutions is in defining how much solute is dissolved in a given amount of solvent. This concept is called concentration. Various words are used to describe the relative amounts of solute. Dilute describes a solution that has very little solute, while concentrated describes a solution that has a lot of solute. One problem is that these terms are qualitative; they describe more or less but not exactly how much.

In most cases, only a certain maximum amount of solute can be dissolved in a given amount of solvent. This maximum amount is called the solubility of the solute. It is usually expressed in terms of the amount of solute that can dissolve in 100 g of the solvent at a given temperature. Table 1 lists the solubilities of some simple ionic compounds. These solubilities vary widely: NaCl can dissolve up to 31.6 g per 100 g of H₂O, while AgCl can dissolve only 0.00019 g per 100 g of H₂O.

When the maximum amount of solute has been dissolved in a given amount of solvent, we say that the solution is saturated with solute. When less than the maximum amount of solute is dissolved in a given amount of solute, the solution is unsaturated. These terms are also qualitative terms because each solute has its own solubility. A solution of 0.00019 g of AgCl per 100 g of H₂O may be saturated, but with so little solute dissolved, it is also rather dilute. A solution of 36.1 g of NaCl in 100 g of H₂O is also saturated but rather concentrated. Ideally, we need more precise ways of specifying the amount of solute in a solution.

In some circumstances, it is possible to dissolve more than the maximum amount of a solute in a solution. Usually, this happens by heating the solvent, dissolving more solute than would normally dissolve at regular temperatures, and letting the solution cool down slowly and carefully. Such solutions are called supersaturated solutions and are not stable; given an opportunity (such as dropping a crystal of solute in the solution), the excess solute will precipitate from the solution.

It should be obvious that some solutes dissolve in certain solvents but not others. NaCl, for example, dissolves in water but not in vegetable oil. Beeswax dissolves in liquid hexane but not water. What is it that makes a solute soluble in some solvents but not others?

The answer is intermolecular interactions. The intermolecular interactions include London dispersion forces, dipole-dipole interactions, and hydrogen bonding. From experimental studies, it has been determined that if molecules of a solute experience the same intermolecular forces that the solvent does, the solute will likely dissolve in that solvent. So, NaCl-a very polar substance because it is composed of ions-dissolves in water, which is very polar, but not in oil, which is generally nonpolar. Nonpolar wax dissolves in nonpolar hexane but not in polar water. This concept leads to the general rule that "like dissolves like" for predicting whether a solute is soluble in a given solvent. However, this is a general rule, not an absolute statement, so it must be applied with care.

Would C₃H₇OH be more soluble in CCl₄ or H₂O? Explain your answer.

Answer

H₂O because both experience hydrogen bonding