the dehydration of Aldol products to synthesize α, β unsaturated carbonyls (enones) |
![]() ![]() |
Read More
Date: 31-10-2019
![]()
Date: 17-10-2020
![]()
Date: 7-2-2016
![]() |
The products of aldol reactions often undergo a subsequent elimination of water, made up of an alpha-hydrogen and the beta-hydroxyl group. The product of this β
-elimination reaction is an α,β-unsaturated aldehyde or ketone. Base-catalyzed elimination occurs with heating. The additional stability provided by the conjugated carbonyl system of the product makes some aldol reactions thermodynamically driven and mixtures of stereoisomers (E & Z) are obtained from some reactions. Reactions in which a larger molecule is formed from smaller components, with the elimination of a very small by-product such as water, are termed Condensations. Hence, the following examples are properly referred to as aldol condensations. Overall the general reaction involves a dehydration of an aldol product to form an alkene:
Figure: General reaction for an aldol condensation
Going from reactants to products simply
Figure: The aldol condensatio example
Example 23.3.2: Aldol Condensation
|
|
التوتر والسرطان.. علماء يحذرون من "صلة خطيرة"
|
|
|
|
|
مرآة السيارة: مدى دقة عكسها للصورة الصحيحة
|
|
|
|
|
نحو شراكة وطنية متكاملة.. الأمين العام للعتبة الحسينية يبحث مع وكيل وزارة الخارجية آفاق التعاون المؤسسي
|
|
|