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Date: 20-12-2018
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Date: 10-3-2019
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Date: 6-11-2018
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Potassium dichromate(VI) solution turns green as it reacts with the iron(II) ions, and there is no way you could possibly detect the color change when you have one drop of excess orange solution in a strongly colored green solution. With potassium dichromate(VI) solution you have to use a separate indicator, known as a redox indicator. These change color in the presence of an oxidizing agent. There are several such indicators - such as diphenylamine sulfonate. This gives a violet-blue color in the presence of excess potassium dichromate(VI) solution.
The two half-equations are:
Combining these gives:
You can see that the reacting proportions are 1 mole of dichromate(VI) ions to 6 moles of iron(II) ions. Once you have established that, the titration calculation is again going to be just like any other one.
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