Monoxides of the 3d metals
المؤلف:
Peter Atkins, Tina Overton, Jonathan Rourke, Mark Weller, and Fraser Armstrong
المصدر:
Shriver and Atkins Inorganic Chemistry ,5th E
الجزء والصفحة:
ص611-612
2025-10-09
258
Monoxides of the 3d metals
The monoxides of most of the 3d metals adopt the rock-salt structure, so it might at first appear that there is little to say about them and that their properties should be simple.
In fact, the actual stoichiometries formed around the ideal composition MO and the structures and properties of these oxides are more interesting, and as a result they have been re-peatedly investigated (Table 24.2). In particular, the compounds provide examples of how mixed oxidation states and defects lead to nonstoichiometry for solids that are nominally TiO, VO, FeO, CoO, and NiO. All these compounds are usually obtained with significant deviations from the nominal MO stoichiometry.
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