Enolate of Unsymmetrical Carbonyl Compounds
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LibreTexts Project
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21-11-2019
1707
Enolate of Unsymmetrical Carbonyl Compounds
Now let’s consider what happens when an unsymmetrical carbonyl is treated with a base. In the case displayed below there are two possible enolates which can form. The removal of the 2o hydrogen forms the kinetic enolate and is formed faster because it is less substituted and thereby less sterically hindered. The removal of the 3o hydrogen forms the thermodynamic enolate which is more stable because it is more substituted.
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