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Simple Benzene Naming

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المصدر:  LibreTexts Project

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20-8-2019

1745

Simple Benzene Naming

Some common substituents, like NO₂, Br, and Cl, can be named this way when it is attached to a phenyl group. Long chain carbons attached can also be named this way. The general format for this kind of naming is:

(positions of substituents (if >1)- + # (di, tri, ...) + substituent)_n + benzene.

For example, chlorine (Cl) attached to a phenyl group would be named chlorobenzene (chloro + benzene). Since there is only one substituent on the benzene ring, we do not have to indicate its position on the benzene ring (as it can freely rotate around and you would end up getting the same compound.)

Figure 8. Example of simple benzene naming with chlorine and NO₂ as substituents.

Figure 9. More complicated simple benzene naming examples - Note that standard nomenclature priority rules are applied here, causing the numbering of carbons to switch.