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Halogens and the Character of the Carbon-Halogen Bond

المؤلف:  ..................

المصدر:  LibreTexts Project

الجزء والصفحة:  .................

9-7-2019

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Halogens and the Character of the Carbon-Halogen Bond

With respect to electronegativity, halogens are more electronegative than carbons. This results in a carbon-halogen bond that is polarized. As shown in the image below, carbon atom has a partial positive charge, while the halogen has a partial negative charge.

The following image shows the relationship between the halogens and electronegativity. Notice, as we move up the periodic table from iodine to fluorine, electronegativity increases.

The following image shows the relationships between bond length, bond strength, and molecular size. As we progress down the periodic table from fluorine to iodine, molecular size increases. As a result, we also see an increase in bond length. Conversely, as molecular size increases and we get longer bonds, the strength of those bonds decreases.