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Major vs minor resonance contributors

المؤلف:  ........

المصدر:  LibreTexts Project

الجزء والصفحة:  ............

10-5-2019

3314

Major vs minor resonance contributors

Different resonance contributors do not always make the same contribution to the overall structure of the hybrid - rather, in many cases one contributor comes closer to depicting the actual bonding picture than another. In the case of carboxylates, contributors A and B below are equivalent in terms of their relative contribution to the hybrid structure. However, there is also a third resonance contributor ‘C, in which the carbon bears a positive formal charge and both oxygens are single-bonded and bear negative charges.

Structure C makes a less important contribution to the overall bonding picture of the group relative to A and B. How do we know that structure C is the ‘minor’ contributor.