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Date: 6-7-2019
1567
Date: 20-5-2017
1739
Date: 24-5-2017
2875
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The acidity of terminal alkynes also plays a role in product determination when vicinal (or geminal) dihalides undergo base induced bis-elimination reactions. The following example illustrates eliminations of this kind starting from 1,2-dibromopentane, prepared from 1-pentene by addition of bromine. The initial elimination presumably forms 1-bromo-1-pentene, since base attack at the more acidic and less hindered 1 º-carbon should be favored. The second elimination then produces 1-pentyne. If the very strong base sodium amide is used, the terminal alkyne is trapped as its sodium salt, from which it may be released by mild acid treatment. (NB One cannot stop the reaction at the terminal alkyne with 2 equivalents of strong base.) However, if the weaker base KOH with heat is used for the elimination, the terminal alkyne salt is not formed, or is formed reversibly, and the initially generated 1-pentyne rearranges to the more stable 2-pentyne via an allene intermediate.
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دواء جديد يعطي الأمل لمرضى الانزلاق الغضروفي
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آلة زمن للمستقبل.."ميتا" تكشف عن نموذج لنظارات الواقع المعزز
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بالفيديو: في مستشفيات العتبة الحسينية.. ممثل المرجعية العليا أول المستقبلين للجرحى اللبنانيين
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