Example 13
What are [H+] and [OH−] for an aqueous solution whose pH is 4.88?
Solution
We need to evaluate the expression
[H+] = 10−4.88
Depending on the calculator you use, the method for solving this problem will vary. In some cases, the “−4.88” is entered and a “10x” key is pressed; for other calculators, the sequence of keystrokes is reversed. In any case, the correct numerical answer is as follows:
[H+] = 1.3 × 10−5 M
Because 4.88 has two digits after the decimal point, [H+] is limited to two significant figures. From this, [OH−] can be determined:
[OH−] = 1×10−14 / 1.3×10−5 = 7.7×10−10 M
Test Yourself
What are [H+] and [OH−] for an aqueous solution whose pH is 10.36?
Answer
[H+] = 4.4 × 10−11 M; [OH−] = 2.3 × 10−4 M
Example 14
The pH of a solution is 8.22. What are pOH, [H+], and [OH−]?
Solution
Because the sum of pH and pOH equals 14, we have
8.22 + pOH = 14
Subtracting 8.22 from 14, we get
pOH = 5.78
Now we evaluate the following two expressions:
[H+] = 10−8.22
[OH−] = 10−5.78
So
[H+] = 6.0 × 10−9 M
[OH−] = 1.7 × 10−6 M
Test Yourself
The pOH of a solution is 12.04. What are pH, [H+], and [OH−]?
Answer
pH = 1.96; [H+] = 1.1 × 10−2 M; [OH−] = 9.1 × 10−13 M