Standard Conditions of Temperature and Pressure
Scientists have chosen a particular set of conditions to use as a reference: 0°C (273.15 K) and 1bar=100kPa=105Pa pressure, referred to as standard temperature and pressure (STP).
STP :T=273.15K and P=1bar=105Pa
Please note that STP was defined differently in the part. The old definition was based on a standard pressure of 1 atm.
We can calculate the volume of 1.000 mol of an ideal gas under standard conditions using the variant of the ideal gas law given in Equation below:
Thus the volume of 1 mol of an ideal gas is 22.71 L at STP and 22.41 L at 0°C and 1 atm, approximately equivalent to the volume of three basketballs. The molar volumes of several real gases at 0°C and 1 atm are given in Table 10.3, which shows that the deviations from ideal gas behavior are quite small. Thus the ideal gas law does a good job of approximating the behavior of real gases at 0°C and 1 atm. The relationships described in Section 10.3 as Boyle’s, Charles’s, and Avogadro’s laws are simply special cases of the ideal gas law in which two of the four parameters (P, V, T, and n) are held fixed.
Thus the volume of 1 mol of an ideal gas is 22.71 L at STP and 22.41 L at 0°C and 1 atm, approximately equivalent to the volume of three basketballs. The molar volumes of several real gases at 0°C and 1 atm are given in Table 10.3, which shows that the deviations from ideal gas behavior are quite small. Thus the ideal gas law does a good job of approximating the behavior of real gases at 0°C and 1 atm. The relationships described in Section 10.3 as Boyle’s, Charles’s, and Avogadro’s laws are simply special cases of the ideal gas law in which two of the four parameters (P, V, T, and n) are held fixed.
Table 5.4.1: Molar Volumes of Selected Gases at 0°C and 1 atm
| Gas |
Molar Volume (L) |
| He |
22.434 |
| Ar |
22.397 |
| H2 |
22.433 |
| N2 |
22.402 |
| O2 |
22.397 |
| CO2 |
22.260 |
| NH3 |
22.079 |
